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UL 94 Flammability Standards and Flame-Retardant Thermoplastics in Manufacturing

In industries like electronics, aerospace, and automotive, fire safety is a top priority. As additive manufacturing (AM) commonly known as 3D printing—continues to revolutionize production, selecting the right flame-retardant thermoplastics is essential for ensuring safety, compliance, and reliability.

What is UL 94?

UL 94 is a flammability standard for plastics established by Underwriters Laboratories (UL) in the USA. It evaluates and classifies plastics based on their burning behavior in different orientations and thicknesses. The standard includes six classifications, ranging from the least to the most flame-retardant materials, helping manufacturers select appropriate materials for fire safety compliance.

UL 94 RatingDefinition of Rating
HBSlow burning on a horizontal part.
V-2Burning stops within 30 seconds on a vertical part, with flaming drips
V-1Burning stops within 30 seconds on a vertical part, without flaming drips
V-0Burning stops within 10 seconds on a vertical part, without flaming drips.
5VBBurning stops within 60 seconds on a vertical part, without flaming drips. Burn-through (holes) may be present.
5VABurning stops within 60 seconds on a vertical part, without flaming drips. No burn-through (no holes).

The following table compares the attributes of UL 94 V-0 and HB ratings:

When discussing UL 94 flame classifications, the HB and V-0 ratings are frequently used. The main difference between these two ratings is the test orientation (horizontal versus vertical) and the level of flame resistance required. The HB classification measures the burn rate to meet specific standards, but it does not ensure that the material will self-extinguish once the flame is removed..

CriteriaUL 94 HB attributesUL 94 V-0 attributes
Flame retardant processNo advanced additives: – Longer to put out fires – May drip or spread flamesHigh-efficiency additives: – Quickly puts out flames – Prevents fire spread
Effect on physical propertiesMore noticeable changes: – Can weaken material due to heat exposureMinor changes: – Might slightly change strength or flexibility
Compliance with safety normsMeets a basic level of flame resistance, may fall short for stringent fire safety demands.Complies with the most demanding fire safety norms, suitable for high-risk environments.

Industrial Applications of Flame Retardant Materials

Automotive Industry

Flame-retardant materials play a crucial role in the automotive industry by ensuring compliance with fire safety regulations. These materials, such as flame-retardant ABS plastics, are commonly used in interior components like dashboards, upholstery, and wiring harnesses. By reducing the risk of fire during collisions or electrical malfunctions, they enhance vehicle safety and durability.

Electronics Industry

Flame-retardant materials are critical in electronics to protect sensitive components and ensure products comply with fire safety standards. These materials are widely used in circuit boards, connectors, and housing materials to minimize fire-related failures and electrical malfunctions, enhancing both safety and longevity.

Consumer Products

Flame-retardant materials are also found in everyday consumer goods such as furniture, appliances, and electronics. For instance, flame-retardant materials in upholstered furniture and bedding help prevent ignition and slow down fire spread, providing an extra layer of safety in homes and workplaces.

Collaborate with 3D printing bureau to choose the best material and optimize build orientation for your project’s needs. Explore our 3D Printing Materials Guide to learn about various plastic and metal materials across technologies.

Discover more about additive manufacturing at projet.my. For assistance, reach out to our applications engineer at [email protected] or +604-2858 335.

HIPS

HIPS is a multifunctional material. It shares many mechanical properties with ABS plastic, but as the name suggests, it has a much higher resistance to impact. This added strength makes HIPS an excellent choice for creating durable 3D-printed parts that can withstand everyday wear and tear.

Suitable for: FDM

Application

  • Prototype
  • End-User part

Application Fields

  • Aerospace: YES
  • Automotive: YES
  • Industrial Machinery: YES
  • Consumer Electronics: YES
  • Automation: YES
  • Medical: YES
  • Education Community: YES

Material Property

  • Density(g/cm3): 1.04
  • Tensile Strength(MPa): 40
  • Flex Modulus(MPa): 1600
  • Elongation(%): 18
  • Heat Distortion Temp(°C): 80
  • Hardness Shore D: –

PMMA-Like Resin

PMMA Like clear resin has high transparency and anti-yellowing, suitable for high transparency applications in non-high temperature environments. The transparent resin has imitation acrylic, glass appearance.

Suitable for: SLA

Application

  • Prototype
  • End-User part

Application Fields

  • Aerospace: YES
  • Automotive: YES
  • Industrial Machinery: YES
  • Consumer Electronics: YES
  • Automation: YES
  • Medical: YES
  • Education Community: YES

Material Property

  • Density(g/cm3): 1.05
  • Tensile Strength(MPa): 40
  • Flex Modulus(MPa): 40
  • Elongation(%): 32
  • Heat Distortion Temp(°C): –
  • Hardness Shore D: 78

Nylon12 Glass Fibre40 Blue-gray

This grey-blue composite nylon powder, enhanced with 40% glass beads, creates 3D-printed parts with exceptional stiffness and heat resistance. Powder reuse rate can reach up to 100%.

Suitable for: SLS

Application

  • Prototype
  • End-User part

Application Fields

  • Aerospace: YES
  • Automotive: YES
  • Industrial Machinery: YES
  • Consumer Electronics: YES
  • Automation: YES
  • Medical: YES
  • Education Community: YES

Material Property

  • Density(g/cm3): 0.72
  • Tensile Strength(MPa): 46
  • Flex Modulus(MPa): 2,800
  • Elongation(%): –
  • Heat Distortion Temp(°C): 160
  • Hardness Shore D: –

Nylon 12 Glass Fibre 30

PA12GB30 is a high-performance material with excellent chemical, mechanical, and thermal properties, ideal for engineering applications. Compared to PA6, it absorbs significantly less moisture, preserving strength and shape in humid environments. With added glass fiber reinforcement, it offers enhanced durability, stiffness, and stability, making it a reliable choice for demanding conditions.

Suitable for: SLS

Application

  • Prototype
  • End-User part

Application Fields

  • Aerospace: YES
  • Automotive: YES
  • Industrial Machinery: YES
  • Consumer Electronics: YES
  • Automation: YES
  • Medical: YES
  • Education Community: YES

Material Property

  • Density(g/cm3): 1.25
  • Tensile Strength(MPa): 62.6
  • Flex Modulus(MPa): 2,340
  • Elongation(%): 6.8
  • Heat Distortion Temp(°C): 160
  • Hardness Shore D: –

Rubber-Like Resin

Rubber-like resin has a low tensile modulus and high elongation at break, making it well-suited for objects that will be bent or compressed.

Suitable for: SLA

Application

  • Prototype
  • End-User part

Application Fields

  • Aerospace: YES
  • Automotive: YES
  • Industrial Machinery: YES
  • Consumer Electronics: YES
  • Automation: YES
  • Medical: YES
  • Education Community: YES

Material Property

  • Density(g/cm3): –
  • Tensile Strength(MPa): 7.9
  • Flex Modulus(MPa): –
  • Elongation(%): 255.1
  • Heat Distortion Temp(°C): –
  • Hardness Shore D: 60-75

ABS-Like Resin

ABS-like resin excels in high precision, providing a smooth surface quality with exquisite detail features. Known for its superior forming dimensional stability, this resin is ideal for the assembly and testing of various engineering models. Achieving a perfect balance between tensile strength and hardness, it prevents brittleness with its high elongation at break, ensuring resistance to breaking.

Suitable for: SLA

Application

  • Prototype
  • End-User part

Application Fields

  • Aerospace: YES
  • Automotive: YES
  • Industrial Machinery: YES
  • Consumer Electronics: YES
  • Automation: YES
  • Medical: YES
  • Education Community: YES

Material Property

  • Density(g/cm3): 1.05-1.13
  • Tensile Strength(MPa): 42-62
  • Flex Modulus(MPa): 60-80
  • Elongation(%): 11-21
  • Heat Distortion Temp(°C): –
  • Hardness Shore D: 75-80

Nylon-Like Resin

Nylon-like resin is a high-strength material known for its excellent durability and long-term stability. It also boasts exceptional toughness and impact resistance.

Suitable for: SLA

Application

  • Prototype
  • End-User part

Application Fields

  • Aerospace: YES
  • Automotive: YES
  • Industrial Machinery: YES
  • Consumer Electronics: YES
  • Automation: YES
  • Medical: YES
  • Education Community: YES

Material Property

  • Density(g/cm3): 1.05-1.15
  • Tensile Strength(MPa): 68
  • Flex Modulus(MPa): 35
  • Elongation(%): 15
  • Heat Distortion Temp(°C): –
  • Hardness Shore D: 75

Hard-Tough Resin

This hard resin boasts higher toughness and impact resistance compared to standard ABS-like resin, making it exceptionally well-suited for mechanical prototypes.

Suitable for: SLA

Application

  • Prototype
  • End-User part

Application Fields

  • Aerospace: YES
  • Automotive: YES
  • Industrial Machinery: YES
  • Consumer Electronics: YES
  • Automation: YES
  • Medical: YES
  • Education Community: YES

Material Property

  • Density(g/cm3): 1.08-1.12
  • Tensile Strength(MPa): 30-60
  • Flex Modulus(MPa): 30-75
  • Elongation(%): 35-52
  • Heat Distortion Temp(°C): 60
  • Hardness Shore D: 75-81

High Temp. Resin

High Temp Resin is characterized by high hardness, strength, modulus, and precision. It exhibits resistance to prolonged heating at 120°C or boiling at 100°C, showcasing excellent mechanical properties, weather resistance, and temperature resistance.

Suitable for: SLA

Application

  • Prototype
  • End-User part

Application Fields

  • Aerospace: YES
  • Automotive: YES
  • Industrial Machinery: YES
  • Consumer Electronics: YES
  • Automation: YES
  • Medical: YES
  • Education Community: NO

Material Property

  • Density(g/cm3): 1.09-1.10
  • Tensile Strength(MPa): 70-85
  • Flex Modulus(MPa): 95-105
  • Elongation(%): 35-40
  • Heat Distortion Temp(°C): 100.5
  • Hardness Shore D: 82-84

General Resin

General resin, known for its high rigidity, proves to be a versatile material ideal for both functional testing and rapid prototype.

Suitable for: SLA

Application

  • Prototype

Application Fields

  • Aerospace: NO
  • Automotive: YES
  • Industrial Machinery: NO
  • Consumer Electronics: YES
  • Automation: YES
  • Medical: NO
  • Education Community: YES

Material Property

  • Density(g/cm3): 1.08-1.13
  • Tensile Strength(MPa): 46-67
  • Flex Modulus(MPa): 46-72
  • Elongation(%): 28-36
  • Heat Distortion Temp(°C): –
  • Hardness Shore D: 78-82

Ultem1010 PEI (Polyetherimide)

PEI is a high-performance industrial-grade thermoplastic known for its strength, durability, and low flammability. This versatile material finds applications in various industries, including automotive, aerospace, medicine, and dentistry.

Suitable for: FDM

Application

  • Prototype
  • End-User part

Application Fields

  • Aerospace: YES
  • Automotive: YES
  • Industrial Machinery: YES
  • Consumer Electronics: NO
  • Automation: YES
  • Medical: NO
  • Education Community: NO

Material Property

  • Density(g/cm3): 1.27
  • Tensile Strength(MPa): 90
  • Flex Modulus(MPa): 3427
  • Elongation(%): 3.3
  • Heat Distortion Temp(°C): 207
  • Hardness Shore D: –

Ultem9085 PEI (Polyetherimide)

PEI is a high-performance industrial-grade thermoplastic known for its strength, durability, and low flammability. This versatile material finds applications in various industries, including automotive, aerospace, medicine, and dentistry.

Suitable for: FDM

Application

  • Prototype
  • End-User part

Application Fields

  • Aerospace: YES
  • Automotive: YES
  • Industrial Machinery: YES
  • Consumer Electronics: NO
  • Automation: YES
  • Medical: NO
  • Education Community: NO

Material Property

  • Density(g/cm3): 1.34
  • Tensile Strength(MPa): 86
  • Flex Modulus(MPa): 2340
  • Elongation(%): 4
  • Heat Distortion Temp(°C): 150
  • Hardness Shore D: –

PEEK (Polyether ether ketone)

PEEK (polyetheretherketone) is a high-performance semi-crystalline industrial thermoplastic known for its exceptional resistance to harsh chemicals, minimal moisture absorption, excellent fire performance, superior mechanical strength over a wide temperature range, and reliable dimensional stability.

Suitable for: FDM

Application

  • Prototype
  • End-User part

Application Fields

  • Aerospace: YES
  • Automotive: YES
  • Industrial Machinery: YES
  • Consumer Electronics: YES
  • Automation: YES
  • Medical: YES
  • Education Community: YES

Material Property

  • Density(g/cm3): 1.29
  • Tensile Strength(MPa): 100
  • Flex Modulus(MPa): 4200
  • Elongation(%): 40
  • Heat Distortion Temp(°C): 140
  • Hardness Shore D: –

PET-CF (Carbon fiber reinforced polyethylene terephthalate)

PET-CF emerges as a superior choice over nylon for printing functional parts in high-humidity environments. Its high-temperature resistance and minimal warping make it ideal for crafting mechanical assembly parts, including automotive accessories and fixtures. In comparison to PETG-CF, PET-CF contains a higher concentration of carbon fibre, resulting in significantly greater strength and high temperature resistance.

Suitable for: FDM

Application

  • Prototype
  • End-User part

Application Fields

  • Aerospace: YES
  • Automotive: YES
  • Industrial Machinery: YES
  • Consumer Electronics: YES
  • Automation: YES
  • Medical: YES
  • Education Community: YES

Material Property

  • Density(g/cm3): 1.29
  • Tensile Strength(MPa): 131
  • Flex Modulus(MPa): 5320
  • Elongation(%): 1.2
  • Heat Distortion Temp(°C): 205
  • Hardness Shore D: –

PAHT-CF (High temperature polyamide carbon fiber reinforced)

A composite of PA and carbon fibre, merges the low water absorption advantage of PA with the high-performance attributes of carbon fibre. This combination yields excellent mechanical and thermal properties that remain robust even in wet conditions. PA+CF is prized for its outstanding chemical resistance, low moisture absorption, and versatile processing capabilities.

Suitable for: FDM

Application

  • Prototype
  • End-User part

Application Fields

  • Aerospace: YES
  • Automotive: YES
  • Industrial Machinery: YES
  • Consumer Electronics: YES
  • Automation: YES
  • Medical: YES
  • Education Community: YES

Material Property

  • Density(g/cm3): 1.06
  • Tensile Strength(MPa): 125
  • Flex Modulus(MPa): 4230
  • Elongation(%): 1.8
  • Heat Distortion Temp(°C): 194
  • Hardness Shore D: –

PLA-CF (Carbon fiber reinforced polylactic acid)

Carbon fibber reinforced PLA, stands out for its remarkable increase in stiffness and strength. This cutting-edge bio-polymer, when combined with recycled carbon fibber reinforcement, results in a higher mechanical properties

Suitable for: FDM

Application

  • Prototype
  • End-User part

Application Fields

  • Aerospace: YES
  • Automotive: YES
  • Industrial Machinery: YES
  • Consumer Electronics: YES
  • Automation: YES
  • Medical: YES
  • Education Community: YES

Material Property

  • Density(g/cm3): 1.22
  • Tensile Strength(MPa): 89
  • Flex Modulus(MPa): 3950
  • Elongation(%): 3.2
  • Heat Distortion Temp(°C): 55
  • Hardness Shore D: –

ESD-safe (Electrostatic discharge)

It exhibits excellent antistatic performance, making it particularly suitable for fields that require ESD protection.

Suitable for: FDM

Application

  • Prototype
  • End-User part

Application Fields

  • Aerospace: YES
  • Automotive: YES
  • Industrial Machinery: YES
  • Consumer Electronics: YES
  • Automation: YES
  • Medical: YES
  • Education Community: YES

Material Property

  • Density(g/cm3): 1.08-1.11
  • Tensile Strength(MPa): 55
  • Flex Modulus(MPa): 2300
  • Elongation(%): 5
  • Heat Distortion Temp(°C): 95
  • Surface Resistance: 107 and 109 ohms Ω

UL 94-V0

It possesses higher mechanical properties and is halogen-free, environmentally friendly, and flame retardant, achieving a UL94V-0 level flame retardancy. This makes the product more fireproof and safer.

Suitable for: FDM

Application

  • Prototype
  • End-User part

Application Fields

  • Aerospace: YES
  • Automotive: YES
  • Industrial Machinery: YES
  • Consumer Electronics: YES
  • Automation: YES
  • Medical: NO
  • Education Community: YES

Material Property

  • Density(g/cm3): 1.05
  • Tensile Strength(MPa): 35
  • Flex Modulus(MPa): 2280
  • Elongation(%): 10
  • Heat Distortion Temp(°C): 100
  • Hardness Shore D: –

ASA (Acrylonitrile styrene acrylate)

ASA shares excellent mechanical properties with ABS but offers additional benefits. It is more resistant to ultraviolet rays and harsh weather conditions, making it particularly suitable for outdoor use. ASA boasts strong toughness, rigidity, and high impact resistance.

Suitable for: FDM

Application

  • Prototype
  • End-User part

Application Fields

  • Aerospace: NO
  • Automotive: YES
  • Industrial Machinery: YES
  • Consumer Electronics: YES
  • Automation: YES
  • Medical: NO
  • Education Community: YES

Material Property

  • Density(g/cm3): 1
  • Tensile Strength(MPa): 45
  • Flex Modulus(MPa): 1900
  • Elongation(%): 30
  • Heat Distortion Temp(°C): 86
  • Hardness Shore D: –

PP (Polypropylene)

Polypropylene (PP) is a popular material in 3D printing, valued for its versatility, strength, and chemical resistance. This lightweight and flexible plastic stands up well to acids, bases, and organic solvents, making it suitable for a range of applications. Additionally, PP is considered food-safe, though standard 3D printing food safety guidelines should still be followed.

Suitable for: FDM

Application

  • Prototype
  • End-User part

Application Fields

  • Aerospace: YES
  • Automotive: YES
  • Industrial Machinery: YES
  • Consumer Electronics: YES
  • Automation: YES
  • Medical: YES
  • Education Community: YES

Material Property

  • Density(g/cm3): 1.05
  • Tensile Strength(MPa): 26
  • Flex Modulus(MPa): 1200
  • Elongation(%): 30
  • Heat Distortion Temp(°C): 60-80
  • Hardness Shore D: –

PC (Polycarbonates)

PC is a high-performance material known for its toughness, heat resistance, dimensional stability, and high optical clarity. It exhibits excellent mechanical properties, high toughness, and impact resistance, making it stable and durable. Additionally, PC offers impressive temperature resistance, with a heat distortion temperature up to 80 ℃.

Suitable for: FDM

Application

  • Prototype
  • End-User part

Application Fields

  • Aerospace: YES
  • Automotive: YES
  • Industrial Machinery: YES
  • Consumer Electronics: YES
  • Automation: YES
  • Medical: YES
  • Education Community: YES

Material Property

  • Density(g/cm3): 1.21
  • Tensile Strength(MPa): 54
  • Flex Modulus(MPa): 1073
  • Elongation(%): 150
  • Heat Distortion Temp(°C): 80
  • Hardness Shore D: –

Nylon / PA (Polyamide)

Nylon is a versatile material known for its good flexibility, wear resistance, and high strength-to-weight ratio. PA12, in particular, exhibits high toughness and impact resistance.

Suitable for: FDM

Application

  • Prototype
  • End-User part

Application Fields

  • Aerospace: YES
  • Automotive: YES
  • Industrial Machinery: YES
  • Consumer Electronics: YES
  • Automation: YES
  • Medical: YES
  • Education Community: YES

Material Property

  • Density(g/cm3): 1.21
  • Tensile Strength(MPa): 50
  • Flex Modulus(MPa): 659
  • Elongation(%): 165
  • Heat Distortion Temp(°C): 100
  • Hardness Shore D: –

TPU (Thermoplastic polyurethane)

TPU material is renowned for its excellent flexibility, high elasticity, tear resistance, wear resistance, cut resistance, sturdiness, and durability.

Suitable for: FDM

Application

  • Prototype
  • End-User part

Application Fields

  • Aerospace: YES
  • Automotive: NO
  • Industrial Machinery: YES
  • Consumer Electronics: YES
  • Automation: YES
  • Medical: NO
  • Education Community: YES

Material Property

  • Density(g/cm3): 1.21
  • Tensile Strength(MPa): 35
  • Flex Modulus(MPa): –
  • Elongation(%): ≥800
  • Heat Distortion Temp(°C): –
  • Hardness Shore D: 95A

PETG (Polyethylene terephthalate glycol)

PETG is a robust material known for its odor neutrality and ease of printing. These characteristics, combined with high impact strength, flexibility, low shrinkage, water resistance, chemical resistance, and high toughness, make PETG an excellent choice for a variety of applications.

Suitable for: FDM

Application

  • Prototype
  • End-User part

Application Fields

  • Aerospace: NO
  • Automotive: YES
  • Industrial Machinery: YES
  • Consumer Electronics: YES
  • Automation: YES
  • Medical: YES
  • Education Community: YES

Material Property

  • Density(g/cm3): 1.27
  • Tensile Strength(MPa): 52
  • Flex Modulus(MPa): 1073
  • Elongation(%): 83
  • Heat Distortion Temp(°C): 64
  • Hardness Shore D: –

ABS (Acrylonitrile butadiene styrene)

ABS is a lightweight material known for its high impact resistance. These characteristics, coupled with a high heat deflection temperature, render ABS suitable for a wide range of applications and environments.

Suitable for: FDM

Application

  • Prototype
  • End-User part

Application Fields

  • Aerospace: YES
  • Automotive: YES
  • Industrial Machinery: YES
  • Consumer Electronics: YES
  • Automation: YES
  • Medical: NO
  • Education Community: YES

Material Property

  • Density(g/cm3): 1.06
  • Tensile Strength(MPa): 40
  • Flex Modulus(MPa): 1203
  • Elongation(%): 30
  • Heat Distortion Temp(°C): 73
  • Hardness Shore D: –

PLA (Polylactic acid)

PLA is an environmentally friendly biopolymer-based material that is both stiff and easy to print. It is available in a wide variety of colours.

Suitable for: FDM

Application

  • Prototype

Application Fields

  • Aerospace: NO
  • Automotive: YES
  • Industrial Machinery: NO
  • Consumer Electronics: YES
  • Automation: YES
  • Medical: NO
  • Education Community: YES

Material Property

  • Density(g/cm3): 1.23
  • Tensile Strength(MPa): 60
  • Flex Modulus(MPa): 1973
  • Elongation(%): 20
  • Heat Distortion Temp(°C): 40
  • Hardness Shore D: –